But it wasn't just Anne's gorgeous purple fringed Gucci frock that got people talking - not to mention the fab matching gladiator heels. The actress opted to accessorise her red carpet styling with a low key school-girl ponytail, and thick-rimmed geek chic spectacles.
Whether the 28-year-old actually needs to wear glasses, or if her eyewear was just a style statement, we're not entirely sure. Nevertheless, it made for an uncharacteristic look from Ms Hathaway - and the MyDaily jury is out on this one...
But what do YOU think of Anne's geek chic specs: hot or not? Let us know your thoughts below!
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