However, this isn't the first time that Connelly has worked with the company. Speaking to WWD, Connelly said, "I've had a long relationship with Shiseido - I worked with them in the eighties on an ad campaign, and have been using their products ever since. It's nice to reconnect with them after so many years".
Judging by her last red carpet appearance in 2011, it's hard to believe that Jennifer is in her forties. Look out for the actress and her flawless skin in her first ad this autumn and take a look below to see the star in her original Shiseido campaign 20 years ago.