The Hollywood couple, who currently have six children, are reportedly planning to add two more to their brood.
Jolie has her heart set on adopting a baby girl from Jordan after visiting Syrian refugees last week, The Sun reports.
A source told the paper: “Angie and Brad’s attitude towards kids is the more, the better — and that once you have several a few more makes no difference.
“She has been particularly touched by the situation in Syria and wants to adopt a child from Jordan to do her bit to help.
“The publicity would help draw the world’s attention to what’s going on there."
The Sun also claims the pair hope to have one more biological child.
The Jolie-Pitt household is currently home to three adopted children — sons Maddox and Pax, and daughter Zahara. Plus, biological twins Knox and Vivienne and daughter Shiloh.
Last week it was revealed the engaged couple posed as a married couple back in 2005.
A lawsuit has claimed they secretly checked into a hotel together posing as a married couple during promotional rounds for their film 'Mr & Mrs Smith' in 2005.
Pitt famously admitted he fell in love with Jolie while working on the movie in 2004, at which time he was still married to Jennifer Aniston.
The claim was revealed in a lawsuit filed by Jolie's British stunt double Eunice Huthart against Rupert Murdoch's News Corporation.