The Hollywood couple, who currently have six children, are reportedly planning to add two more to their brood.
Jolie has her heart set on adopting a baby girl from Jordan after visiting Syrian refugees last week, The Sun reports.
A source told the paper: “Angie and Brad’s attitude towards kids is the more, the better — and that once you have several a few more makes no difference.
“She has been particularly touched by the situation in Syria and wants to adopt a child from Jordan to do her bit to help.
“The publicity would help draw the world’s attention to what’s going on there."
The Sun also claims the pair hope to have one more biological child.
The Jolie-Pitt household is currently home to three adopted children — sons Maddox and Pax, and daughter Zahara. Plus, biological twins Knox and Vivienne and daughter Shiloh.
Last week it was revealed the engaged couple posed as a married couple back in 2005.
A lawsuit has claimed they secretly checked into a hotel together posing as a married couple during promotional rounds for their film 'Mr & Mrs Smith' in 2005.
Pitt famously admitted he fell in love with Jolie while working on the movie in 2004, at which time he was still married to Jennifer Aniston.
The claim was revealed in a lawsuit filed by Jolie's British stunt double Eunice Huthart against Rupert Murdoch's News Corporation.
Angelina Jolie with first husband Jonny Lee Miller
Angelina Jolie with her mother Marcheline Bertrand
Angelina Jolie with her brother James Haven
Angelina Jolie with second husband Billy Bob Thornton
Angelina Jolie and Billy Bob carried vials of each other's blood
Angelina Jolie and Billy Bob Thornton
Angelina Jolie with her father Jon Voight
Angelina Jolie with her Oscar for 'Girl Interrupted' in 2000
Angelina Jolie, vamping it up, around the time of 'Lara Croft'
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Angelina Jolie with her first child, Maddox
Angelina Jolie with her adopted daughter, Zahara
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Angelina Jolie with Brad Pitt following his divorce from Jennifer Aniston
Angelina Jolie with Brad Pitt - a world super brand called 'Brangelina'
... with the power to draw attention to developing world concerns
Brad Pitt and Angelina Jolie
Angelina Jolie with her adopted daughter Zahara
Angelina Jolie with Brad Pitt at the premiere of 'A Mighty Heart'
Angelina Jolie with Brad Pitt
Angelina Jolie with Brad Pitt
Angelina Jolie pregnant in Cannes 2008
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Angelina Jolie in the Oval Office in Washington
Angelina Jolie with William Hague in London
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Angelina Jolie with an award for her charity work
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Angelina Jolie with Brad Pitt at the premiere of 'World War Z'
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