Lavigne wore a black Monique Lhuillier gown to float down the aisle at the Chateau de la Napoule on the French Riviera. Not only did she do gothic-themed gorgeousness (complete with a bouquet of black roses) but Chad was also in a black two-piece suit. Think matchy-matchy pop star and her rock star man.
While Avril - as ever - went a little too heavy on the black eye makeup, we salute the fact that she shrugged off wearing traditional white to take her second jaunt down the aisle (she was married to Deryck Whibley from Sum 41 back in 2006, remember?)
For brides looking for something different on the big day, here's a gallery of coloured wedding dresses guaranteed to keep all eyes on you when it comes to your own WOW wedding day...
The full interview appears in the new edition of Hello! magazine which is on sale now.