The new Mrs Kardashian West shared the following photo with the caption: "OMG I met Sam Smith! He's on Jimmy Kimmel tonight too. Tune in! Xo"
Smith, who performed on the show with Disclosure, was pretty star-struck too as he posted the same photo to his own Instagram page with the caption: "So so good to meet the outrageously beautiful @kimkardashian xx".
Kim did that signature Hollywood glamour thing in a cream strapless bodice with matching silk palazzo trousers and a silk turquoise kimono-esque robe all by Ulyana Sergeenko.
Plunging? Check. Cinched at the waist check? Slicked back glamazon hair by styled by Chris McMillan? Check.
Kim opened up about her now infamous wedding day and revealed that her sisters enjoyed the bubbly:
"Khloe drank a little too much, so I had to wake her up. She was laying down sleeping, getting her makeup done for the wedding," Kim told Kimmel.
"They had to do it while she was sleeping. She was so hungover! I think everyone just had such a good time at Versailles, they drank way too much."
LOVE KIM'S SUPER GLAM STYLE? Take a look through this gallery to see more look's from Kim Kardashian West. She's still about a figure flaunting ensemble but there is less bodycon these days.
MORE! Watch all the latest of Kim right here.