As the couple smiled and posed for photos on the red carpet at the Nokia Theatre in Los Angeles, it became clear that Ellen and Portia were the best dressed stars there this year.
Ellen, 56, was dressed in a white suit and shirt by Yves Saint Laurent. Portia, 41, turned heads in a plunging electric blue jumpsuit by Lebanese designer Zuhair Murad which she paired with Giuseppe Zanotti shoes.
The television presenter was successful on the night, too - Ellen picked up the award for Favourite Daytime TV Host.
Sadly, we won't be seeing the star on stage at the Oscars this year.
Neil Patrick Harris - best known for playing Barney in the comedy series How I Met Your Mother - will replace Ellen at the 2015 Academy Awards.
Despite last year's success, Ellen "was reluctant even then to do it, and didn't want to do it for the 2015 ceremony," Variety reports.
Let's hope Harris can follow in Ellen's footsteps - we want to see another great Oscars selfie.
More from this year's People's Choice Awards red carpet below:
In other news, are Ellen and Portia having a baby?