Firstly, everybody wanted to see what Amal was wearing, and she didn't disappoint. The human rights lawyer wowed in a black Dior Haute Couture gown, which she accessorised with statement Harry Winston earrings, and long white gloves, which, she said, "are just my own", reports E! News.
She worked full lashes, deep red lips and polished waves, giving off an old-school Hollywood vibe.
George looked dapper in his wedding tux (cute), creating the perfect matching monochrome look with Amal.
It was a big night for George, who received the Cecil B. DeMille Award for lifetime achievement in his career.
And, guess what? He made an uncharacteristically gushy speech after being introduced on stage by his former ER co-star Julianna Marguiles, and Oceans Eleven co-star Don Cheadle.
After complimenting everyone in the room with him for chasing their dreams like he has, he turned the talk around to Amal and said, "I've had a pretty good year myself. Listen: It's a humbling thing when you find someone to love- even better when you've been waiting your whole life. And when your whole life is 53 years, Amal, whatever alchemy it is that brought us together, I couldn't be more proud to be your husband."
Then, he spoke about the unity marches in Paris in the wake of the Charlie Hebdo shootings, saying, "And one last thing: to reiterate what we've all been talking about, today was an extraordinary day.
"There were millions of people who marched not just in Paris, but around the world. And they were Christians and Jews and Muslims. They were leaders of countries all over the world. And they didn't march in protest; they marched in support of the idea that we will not walk in fear. We won't do it. So, Je Suis Charlie. Thank you."
See ALL the stars and style from the glitzy event in our gallery below: