The minute-long teaser opens with James on the phone to Adele, waiting to pick her up and reciting lyrics from her hit song, ‘Hello’: “It’s me, I was wondering if after all these years you’d like to meet.”
Wonder if he’s referring to that Brit Awards moment mishap…
As the pair drive around what appears to be London, they sing and bop along to her hits ‘Rolling In The Deep’ and ‘Hello’, while Adele also discusses her forthcoming tour, and asks James - perhaps unwisely - for hair advice.
The skit is due to air on Wednesday during his US talk show, ‘The Late, Late Show’.
Adele joins a long list of A-list stars to have taken a spin with James as part of his Carpool Karaoke sketches, such as Mariah Carey, Stevie Wonder and Justin Bieber, who enjoyed it so much he came back for a second go.
More recently, One Direction all piled into James’s car for a Carpool Karaoke special, belting out some of their biggest hits, including ‘What Makes You Beautiful’, ‘Story of My Life’ and ‘Drag Me Down’, with their unofficial fifth member (sorry Zayn).
Meanwhile, Adele is set to kick off her world tour in Belfast at the end of next month, off the back of her monster hit album, ‘25’.
She’ll be playing dates all over the UK, before hitting the road around Europe, and eventually arriving in States in the summer.