As you’d expect, Brad gets a pretty hilarious grilling, facing questions about everything from Angelina Jolie - “what’s it like living in her shadow?” - to his previous drug use.
Brad split from Jennifer in 2005
However, midway through the clip, Zach goes one step further and asks Brad if meeting Angelina was like everyone’s favourite TV romance…. Ross and Rachel’s in ‘Friends’.
At this, Brad keeps his cool, and if anything, it seems he’s doing his best to stifle the giggles.
Zach then plays the actor some music to jog his memory, in the form of the show’s theme tune. Amazing.
While Brad is always up for a laugh, one prankster faced the actor’s wrath when he attempted to physically attack the star at a movie premiere earlier this year.
Serial prankster Vitalii Sediuk was led away by police when he attacked Brad at the ‘Maleficent’ film premiere. He was then booked on suspicion of misdemeanor battery.
Watch Brad’s full Funny Or Die interview above...