A former Archbishop of Canterbury reportedly wrote to police in support of the then Bishop of Gloucester, who was being investigated for sex offences in 1993.
The letter has come to light as a result of a Freedom of Information Act request submitted to the Crown Prosecution Service.
In the letter, Lord Carey said Peter Ball was in "torment" because of the investigation, according to the BBC.
The Church of England (CoE) apologised "unreservedly" to Ball's victims in response to the letter last night.
In October Ball was jailed for a string of historic offences, including two counts of indecent assault.
While Bishop of Lewes, he hand-picked 18 vulnerable victims to commit acts of "debasement" in the name of religion, such as praying naked at the altar and encouraging them to submit to beatings.
According to the BBC, in one of the letters written in 1993, Lord Carey said it was "improbable" that Ball was guilty of the allegations made against him.
Speaking after Ball's sentencing in October, Lord Carey denied the Church of England had been involved in a cover-up, saying: "I greatly regret the fact that, during my tenure as Archbishop of Canterbury, we dealt inadequately with Peter Ball's victims and gave too much credence to his protestations.
"Allegations by some that my actions amounted to a cover-up or collusion with the abuser are wrong. I have always insisted upon the highest standards of holiness of life from all who are ordained."
In a statement released by the CoE in response to the letters, it said: "It is a matter of deep shame and regret that a bishop in the Church of England was sentenced earlier this year for a series of offences over 15 years against 18 young men known to him.
"There are no excuses whatsoever for what took place, nor for the systematic abuse of trust perpetrated by Peter Ball.
"We apologise unreservedly to those survivors of Peter Ball's abuse and pay tribute to their bravery in coming forward.
"They have had to endure a long wait for justice over decades. We also remember Neil Todd, whose bravery in 1992 enabled others to come forward but who took his own life before Peter Ball's conviction or sentencing."
The CoE added that Ball had "systematically abused the trust of the victims" and abused the trust placed in him by the church and others, "maintaining a campaign of innocence for decades until his final guilty plea earlier this year".