Angelina Jolie have her moment alone to show off her gorgeous pleated Elie Saab dress to the cameras - while he looked on adoringly.
George Clooney's girlfriend was stunning in a modern LBD. Photo: PA
And they weren't the only star couple on the red carpet; George Clooney and girlfriend Stacey Keibler also stepped out together, with the former wrestler looking pretty and sophisticated in a bold-shouldered LBD.
Other stars at the event included Charlize Theron, Tom Hanks, Gary Oldman, Olivia Wilde.
The list of winners are:
Best Picture: Melancholia
Best Director: Terrence Malick, The Tree of Life
Best Actor: Brad Pitt, Moneyball, The Tree of Life
Best Actress: Kirsten Dunst, Melancholia
Best Supporting Actor: Albert Brooks, Drive
Best Supporting Actress: Jessica Chastain, The Tree of Life, Take Shelter, The Help
Best Screenplay: A Separation, Asghar Farhadi
Best Cinematography: The Tree of Life, Emmanuel Lubezki
Best Non-fiction Film: Cave of Forgotten Dreams, Werner Herzog
Best Foreign Language Film: A Separation, Asghar Farhadi
Best Experimental Film: Seeking the Monkey King, Ken Jacobs
See all the pics from the 23rd Palm Springs International Film Festival below: