On Monday night, however, there was something unusual about Jolie's look.
The actress attended the New York premiere for HBO's The Normal Heart in one of her favourite styles - a black strapless dress. It looked great, but unfortunately her cheekbone appeared to be covered in white powder...
Still, it doesn't make us any less excited about seeing the Hollywood star in the new Disney movie Maleficent.
Angelia plays the iconic villain from the 1959 classic Sleeping Beauty and strangely, her face has to be pretty white for the role too.
Perhaps she was bringing her latest character's look to the red carpet? Or perhaps Angelina is more like us than we though. Sometimes, makeup goes wrong when you get ready for a night out in a hurry.
LOVE ANGELINA? See her style evolution below:
Go behind-the-scenes on the Maleficent set with Angelina and her co-star in the film, Elle Fanning: