The actress looked stunning at a photo call for the film at the Corinthia Hotel in London on Friday, wowing in a ruched Atelier Versace white gown.
But the best bit? Those kooky Christian Louboutin heels that look like they've come straight out of a magical forest themselves - that's how you rock villainous Disney character chic. (She also wore a black version in Paris last week).
Ange finished the look with backcombed hair and a slick of bright red lippie, and was joined on the red carpet by her co-star Elle Fanning.
Directed by Robert Stromberg, Maleficent is the much-anticipated new Disney film.
It is the untold story of Disney's most iconic villain from the 1959 classic "Sleeping Beauty."
A beautiful, pure-hearted young woman with stunning black wings, Maleficent has an idyllic life growing up in a peaceable forest kingdom, until one day when an invading army of humans threatens the harmony of the land.
Maleficent rises to be the land's fiercest protector, but she ultimately suffers a ruthless betrayal - an act that begins to turn her pure heart to stone.
Bent on revenge, Maleficent faces an epic battle with the king of the humans and, as a result, places a curse upon his newborn infant Aurora. As the child grows, Maleficent realises that Aurora holds the key to peace in the kingdom - and to Maleficent's true happiness as well.
Excited, us? Noooo. #Bigkidsatheart.
LOVE ANGELINA'S AMAZING STYLE? She's the queen of classic chic, and is always perfectly turned out. Look back at this Hollywood A-lister's style evolution in our gallery below:
MORE! See a sneak peek of the film and watch Angelina chat about the role in the video below: