Well this is GLORIOUS.
"Writer Miles Chapman (R) and Erica Chapman attend the premiere of 'Cybergeddon' at Pacfic Design Center on September 24, 2012 in West Hollywood, California." That's according to the picture wire we use.
According to us, the couple has somehow harnessed the power of the dazzling sun and transformed it into outfits which (presumably) were intended to occupy the "matching" area of the clothing spectrum but have sadly (or GLORIOUSLY) overshot and ended up in CLASHTASTIC VALLEY.
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Bonus Fact: IMDB tells us that Miles (bright of tie and rolled up of jean) is credited with special thanks in a short film called Boob Jobs & Jesus.
And for more couple style matches...