The 20-year-old Victoria’s Secret Angel stars on the cover, and in a sultry shoot inside, alongside fellow supermodels Anna Ewers and Imaan Hammam.
French fashion photographer Patrick Demarchelier shot the images, including the fully-nude black and white image below.
In the accompanying interview, Hill reveals both she and her family were surprised when she was scouted as a model aged 14.
“I was, like, the opposite of cool. Obsessed with Harry Potter,” she said.
“I had all this frizzy hair I didn’t know what to do with; I wore my sisters’ hand-me-downs, which I was too tall for, so nothing ever fitted.”
Despite originally thinking the photographer who said she should be a model was “insane”, Hill’s career skyrocketed after she was first cast by Victoria’s Secret in 2014.
To see the full shoot, pick up the February issue of Vogue in shops now.
You can also scroll down for a sneak preview.