All smiles: Dev and Freida walk the red carpet at the 2011 Toronto International Film Festival. Photo:Getty Images
While Dev was playing the supportive boyfriend in a black suit and shirt, Freida simply sparkled as the leading lady, in a shimmering beaded Valentino dress and studded sandals.
A chic chignon, immaculate makeup and bejwelled droplet earrings completed the winning red carpet ensemble.
Leading lady: Freida dazzled in beaded Valentino at the Trishna premiere. Photo: Getty Images
Freida stars in Trishna alongside actor Riz Ahmed - a film based on the story Tess of the D'Urbervilles, but set in India.
Click on our gallery below to see all the stars at this year's TIFF: