17/02/2014 03:37 GMT | Updated 22/02/2014 06:59 GMT

Baftas 2014: Tinie Tempah High-Fives Prince William, Poses With Brad Pitt And Angelina Jolie (PICTURES)

It was a huge night for Tinie Tempah at the 2014 Bafta Awards on Sunday - as he opened the show with singer Laura Mvula - and he didn't miss the opportunity to high-five royalty.

Tinie may have been at one of the entertainment industry's most formal events, but the London rapper lightened-up the mood inside the Royal Opera House as he slapped hands with Prince William on the front row.

Tinie Tempah high-fives Prince William

Wills, the academy's president, was on hand to present Dame Helen Mirren with the British Academy fellowship, its highest accolade.

Later in the evening, Tinie continued making friends in high places as he hung out with Brad Pitt and Angelina Jolie at the Grey Goose after party.

The 25-year-old posed between the movie star power couple in their matching suits, before having a good ol' natter with Ange.

The pair flew into London to attend the event in support of '12 Years A Slave', which Brad served as a producer on.

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Photo gallery Baftas 2014: Red Carpet See Gallery