‘Take Me To Church’ signer Hozier is also on the bill, along with Chvrches, George Ezra, ‘The Voice’ coach Tom Jones, Ella Henderson and Ella Eyre.
This year is V’s 20th anniversary, and Calvin has shared his excitement ahead of the August event.
“V Festival is always an incredible time and I can't wait to headline it this year. See you there,” he says.
“V is for victory, V is for voodoo, V is for vacuum cloud, V is for very very very very excited,” adds Kasabian’s Serge Pizzorno. “See you in the fields!”
The 2-day festival takes place on the 22 and 23 August. See the full line-up and day splits here.
Tickets will go on sale on Friday 6 March, at 9am.