The TV presenter was just one of the celebrity guests at the star-studded awards show, but still managed to shine with her outfit, which saw her pair her metallic gown with a pair of high heel shoes.
In what we can only assume was an act of solidarity with Angelina Jolie (yeah, alright, probably not), she was photographed perfecting a leg-bomb on the red carpet, while also sporting her omnipresent ‘Leenie’ necklace.
Myleene was at the event to present stand-up comedian Alan Carr with the Icon Award for Outstanding Achievement, but before he took to the stage, she also shared stories about her children’s acceptance of the LGBTQ community.
But Myleene wasn’t the only star to turn heads on the red carpet, with Kelly Brook also making an impression in a pink satin dress.
She was in attendance with her current beau, Jeremy Parisi, just days after they sparked speculation they had married in secret, when she was seen sporting a little something extra on her ring finger.
During the ceremony, Kelly presented the Most Stylish Man award to Pietro Boselli, best known as the UCL lecturer whose Instagram page blew up last year, when he became dubbed the “world’s sexiest maths teacher”.
Other big winners on the night included Rylan Clark-Neal, Wentworth Miller and singer/songwriter MNEK, who also performed ‘Never Forget You’ during the ceremony.