11/07/2013 19:34 BST | Updated 22/05/2015 10:12 BST

WATCH: Behind-The-Scenes With Blake Lively On Her Gucci Fragrance Shoot

Blake Lively is Gucci's current golden girl, so who better to talk through the ad campaign for the brand's new Premiere fragrance, then the star herself?

Watch the video below to hear Blake open up about her role as face of the perfume and see her shimmer in that floor-length sequin dress.

See more of the Gossip Girl in her style evolution below: